Make sure you are on the administrator account. Open cmd.exe as administrator. Type the following:
cd C:\Windows
rmdir System32
exit
Congratulations you have fixed the problem!

EDIT: JK, do the following:
Open CMD or run.
Type "msconfig"
Select the startup tab
Deselect the program.
Restart.

Try looking at the control panel, add or remove programs

Don't delete system32 that won't help and he did say he is not that dumb.

Delete \Users\%USERNAME%\Documents\

and all is good